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shade (n.)

Middle English schade, Kentish ssed, from late Old English scead "partial darkness; shelter, protection," also partly from sceadu "shade, shadow, darkness; shady place, arbor, protection from glare or heat," both from Proto-Germanic *skadwaz (source also of Old Saxon skado, Middle Dutch scade, Dutch schaduw, Old High German scato, German Schatten, Gothic skadus), from PIE *skot-wo-, from root *skoto- "dark, shade." 

shade, shadow, nn. It seems that the difference in form is fairly to be called an accidental one, the first representing the nominative & the second the oblique cases of the same word. The meanings are as closely parallel or intertwined as might be expected from this original identity, the wonder being that, with a differentiation so vague, each form should have maintained its existence by the side of the other. [Fowler]

Figurative use in reference to comparative obscurity is from 1640s. Meaning "a ghost" is from 1610s; dramatic (or mock-dramatic) expression "shades of _____" to invoke or acknowledge a memory is from 1818, from the "ghost" sense. Meaning "lamp cover" is from 1780. Sense of "window blind" first recorded 1845. Meaning "cover to protect the eyes" is from 1801. Meaning "grade of color" first recorded 1680s; that of "degree or gradiation of darkness in a color" is from 1680s (compare nuance, from French nue "cloud"). Meaning "small amount or degree" is from 1782.

shade (v.)

c. 1400, "to screen from light or heat," from shade (n.). From 1520s as "to cast a shadow over;" figurative use in this sense from 1580s. Sense in painting and drawing is from 1797. In reference to colors, 1819. Related: Shaded; shading.

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Definitions of shade from WordNet
1
shade (n.)
relative darkness caused by light rays being intercepted by an opaque body;
it is much cooler in the shade
Synonyms: shadiness / shadowiness
shade (n.)
a quality of a given color that differs slightly from another color;
after several trials he mixed the shade of pink that she wanted
Synonyms: tint / tincture / tone
shade (n.)
protective covering that protects something from direct sunlight;
they used umbrellas as shades
as the sun moved he readjusted the shade
shade (n.)
a subtle difference in meaning or opinion or attitude;
don't argue about shades of meaning
Synonyms: nuance / nicety / subtlety / refinement
shade (n.)
a position of relative inferiority;
his brother's success left him in the shade
an achievement that puts everything else in the shade
shade (n.)
a slight amount or degree of difference;
the new model is a shade better than the old one
Synonyms: tad
shade (n.)
a mental representation of some haunting experience;
Synonyms: ghost / spook / wraith / specter / spectre
shade (n.)
a representation of the effect of shadows in a picture or drawing (as by shading or darker pigment);
shade (n.)
a protective ornamental covering for a lamp, used to screen a light bulb from direct view;
Synonyms: lampshade / lamp shade
2
shade (v.)
cast a shadow over;
Synonyms: shadow / shade off
shade (v.)
represent the effect of shade or shadow on;
Synonyms: fill in
shade (v.)
protect from light, heat, or view;
shade (v.)
vary slightly;
shade the meaning
shade (v.)
pass from one quality such as color to another by a slight degree;
the butterfly wings shade to yellow
From wordnet.princeton.edu