1510s, "officer who has charge of a post-station and provides post-horses," from post (n.3) + master (n.). Later "official who has superintendence of a post office." Postmaster general "chief of a postal system" is by 1620s.
post-impressionism
Post-it
postlude
postman
postmark
postmaster
post-millennial
postmistress
post-modern
postmodernism
post-mortem