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smug (adj.)

1550s, "trim, neat, spruce, smart," possibly an alteration of Low German smuk "trim, neat," from Middle Low German smücken "to adorn" (originally "to dress," secondary sense of words meaning "to creep or slip into"), from the same source as smock. The meaning "having a self-satisfied air" is from 1701, an extension of the sense of "smooth, sleek" (1580s), which was commonly used of attractive women and girls. Related: Smugly; smugness.

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Definitions of smug from WordNet

smug (adj.)
marked by excessive complacency or self-satisfaction;
a smug glow of self-congratulation
Synonyms: self-satisfied
From wordnet.princeton.edu