1650s, "a covering or protection for the knee," from knee (n.) + cap (n.). Meaning "bone in front of the knee joint" is from 1869; the verb in the underworld sense of "to shoot (someone) in the knee" as punishment is attested by 1975. Related: Kneecapped.
They kneecapped the industrialist
knave
knavery
knavish
knead
knee
kneecap
knee-deep
knee-high
knee-jerk
kneel
kneepad