"made, done, procured, or furnished 'at the time,'" hence "unpremeditated," 1650s, from Medieval Latin extemporaneus, from Latin ex tempore (see extempore). Earlier was extemporal (1560s); extemporanean (1620s). Related: Extemporaneously; extemporaneousness.
an extemporaneous piano recital
exsanguinate
exsert
exsiccate
exsiccation
extant
extemporaneous
extemporary
extempore
extemporize
extend
extended