late 15c., "act of reducing to nothing;" see annul + -ment. Meaning "act of declaring invalid" (a statute, marriage, etc.) is recorded from 1660s; earlier in this sense was annulling (late 14c.).
annually
Annuit Coeptis
annuity
annul
annular
annulment
annulus
annunciate
annunciation
annus mirabilis
anode